The
mined ore is usually crushed into small chunks
and heaped on an impermeable plastic and/or
clay lined leach pad where it can be irrigated
with a leach solution to dissolve the valuable
metals. While sprinklers are occasionally
used for irrigation, more often operations
use drip irrigation to minimize evaporation,
provide more uniform distribution of the
leach solution, and avoid damaging the exposed
mineral. The solution then percolates through
the heap and leaches both the target and
other minerals. This process, called the "leach
cycle," generally takes from one or
two months for simple oxide ores (e.g., most
gold ores) to two years (for nickel laterite
ores). The leach solution containing the
dissolved minerals is then collected, treated
in a process plant to recover the target
mineral and in some cases precipitate other
minerals, and then recycled to the heap after
reagent levels are adjusted. Ultimate recovery
of the target mineral can range from 30%
of contained (run-of-mine dump leaching sulfide
copper ores) to over 90% for the easiest
to leach ores (some oxide gold ores).
In recent years, the addition of an agglomeration
drum has improved on the heap leaching process
by allowing for a more efficient leach. The
rotary drum agglomerator works by taking
the crushed ore fines and agglomerating them
into more uniform particles. This makes it
much easier for the leaching solution to
percolate through the pile, making its way
through the channels between particles.
The addition of an agglomeration drum also
has the added benefit of being able to pre-mix
the leaching solution with the ore fines,
to achieve a more concentrated, homogeneous
mixture, and allowing the leach to begin
prior to the heap.

Precious metals
The crushed ore is irrigated with a dilute
alkaline cyanide solution. The solution containing
the dissolved precious metals ("pregnant
solution") continues percolating through
the crushed ore until it reaches the liner
at the bottom of the heap where it drains
into a storage (pregnant solution) pond.
After separating the precious metals from
the pregnant solution, the dilute cyanide
solution (now called "barren solution")
is normally re-used in the heap-leach-process
or occasionally sent to an industrial water
treatment facility where the residual cyanide
is treated and residual metals are removed.
In very high rainfall areas, such as the
tropics, in some cases there is surplus water
that is then discharged to the environment,
after treatment, posing possible water pollution
if treatment is not properly carried out.
The production of one gold ring through this
method, can generate 20 tons of waste material.
During the extraction phase, the gold ions
form complex ions with the cyanide:

Recuperation of the gold is readily achieved
with a redox-reaction:

The
most common methods to remove the gold from
solution are either using activated
carbon to selectively absorb it, or the
Merrill-Crowe process where zinc powder
is added to cause a precipitation of gold
and zinc. The fine product can be either
doré (gold-silver bars) or zinc-gold
sludge that is then refined elsewhere.
Copper Ores
The method is similar to the cyanide method,
above, except sulfuric acid is used to dissolve
copper from its ores. The acid is recycled
from the solvent extraction circuit
and reused on the leach pad. A byproduct
is iron sulfate, jarosite, which is produced
as a byproduct of leaching pyrite, and sometimes
even the same sulfuric acid that is needed
for the process. Both oxide and sulfide ores
can be leached, though the leach cycles are
much different and sulfide leaching requires
a bacterial or "bio-leach" component.
The largest copper heap leach operations
are in Chile, Peru, and the southwestern
United States.
Although the heap leaching is a low cost-process,
it normally has recovery rates of 60-70%,
although there are exceptions. It is normally
most profitable with low-grade ores. Higher-grade
ores are usually put through more complex
milling processes where higher recoveries
justify the extra cost. The process chosen
depends on the properties of the ore.
The final product is cathode copper.
Nickel Ores
The method is an acid heap leaching method
like that of the copper method in that it
utilises sulfuric acid instead of cyanide
solution to dissolve the target minerals
from crushed ore. The amount of sulfuric
acid required is much higher than for copper
ores (as high as 1,000 kg of acid per tonne
of ore, but 500 kg is more common.) The method
was originally patented by Australian miner
BHP Billiton and is being commercialized
by Cerro Matoso S.A. in Colombia,
Vale in Brazil, and European Nickel PLC for
the rock
laterite deposits of Turkey, Talvivaara mine
in Finland, Balkans, and the Philippines.
There currently are no operating commercial
scale nickel laterite heap leach operations,
but there is a sulphide HL operating in Finland.
Nickel recovery from the leach solutions
is much more complex than for copper and
requires various stages of iron and magnesium
removal, and the process produces both leached
ore residue ("ripios") and chemical
precipitates from the recovery plant (principally
iron oxide residues, magnesium sulfate and
calcium sulfate) in roughly equal proportions.
Thus, a unique feature of nickel heap leaching
is the need for a tailings disposal area.
The final product can be nickel hydroxide
precipitates (NHP) or mixed metal hydroxide
precipitates (MHP), which are then subject
to conventional smelting to produce metallic
nickel.
Uranium Ores
Similar to copper oxide heap leaching, also
using dilute sulfuric acid. Rio Tinto is
commercializing this technology in Namibia
and Australia, the French nuclear power company
Areva in Niger (two mines) and Namibia, and
several other companies are studying its
feasibility.
The final product is yellowcake and requires
significant further processing to produce
fuel-grade feed.
Apparatus
While most mining companies have shifted
from a previously accepted sprinkler method
to the percolation of slowly dripping choice
chemicals (cyanide or sulfuric acid) closer
to the actual ore bed,] heap
leach pads have not changed too much throughout
the years. There are still four main categories
of pads: conventional, dump leach, Valley
Fills, and on/off pads.]
Typically, each pad only has a single, geomembrane
liner for each pad, with a minimum thickness
of 1.5mm (usually it is thicker).
The simplest in design, conventional pads
are used for mostly flat or gentle areas
and hold thinner layers of crushed ore. Dump
leach pads hold more ore and can usually
handle a less flat terrain. Valley Fills
are pads situated at valley bottoms or levels
that can hold everything falling into it.
On/off pads involve the use of putting significantly
larger loads on the pads, and removing it
and reloading it after every cycle.
Many
of these mines, which previously had digging
depths of about 15 meters, are digging
deeper than ever before to mine materials
(approximately 50 meters, sometimes more),
which means that, in order to accommodate
all of the ground being displaced, pads will
have to hold higher weights from more crushed
ore being contained in a smaller area. With
that increase in build up comes in potential
for decrease in yield
or ore quality, as well as potential either
weak spots in the lining or areas of increased
pressure buildup. This build up still has
the potential to lead to punctures in the
liner. As of 2004 cushion fabrics, which
could reduce potential punctures and their
leaking, were still being debated due to
their tendency to increase risks if too much
weight on too large a surface was placed
on the cushioning.
In addition, some liners, depending on their
composition, may react with salts in the
soil as well as acid from the chemical leaching
to affect the successfulness of the liner.
This can be amplified over time.